Molecular conductors with mercury-containing anions: structure–property relationship
نویسندگان
چکیده
منابع مشابه
Physical Properties of Some ET-Based Organic Metals and Superconductors with Mercury Containing Anions
Because of mercury atoms capability of forming the compounds with various coordination, the application of the electrolytes with Hg containing anions in electrochemical oxidation of ET (bis(ethylenedithio)tetrathiafulvalene) results in the formation of ET salts with the orrions of different composition. The properties of organic metals and superconductors are briefly described for three famille...
متن کاملMolecular Conductors with Two-chain Orbitals
We investigate a theoretical model applicable to molecular conductors, such as TTP and M(dmit)2 salts [M=Ni, Pd, Pt], whose charge carriers orig inate from two kinds of molecular orbitals. The model Hamiltonian consists of two independent Hubbard chains. The degree of charge transfer between the two chains is calculated. The results qualitatively agree with some experimental data.
متن کاملMagnetism of Molecular Conductors
The study of the magnetic properties of molecular conductors has experienced, during the last decades, a very significant evolution, comprising systems of increasing molecular complexity and moving towards multifunctional materials, namely by their incorporation in conducting networks of different paramagnetic centers. In this context, molecular magnetic conductors have emerged at the intersect...
متن کاملRoom-temperature silver-containing liquid metal salts with nitrate anions.
The synthesis, structural, thermal and electrochemical properties of fluorine-free silver-containing ionic liquids are presented. The ionic liquid cations are formed by a silver(i) ion surrounded by two 1-alkylimidazole ligands, with the counter anions being nitrate ions. Depending on the alkyl chain length, the complexes were found to be liquids at room temperature or melting slightly above th...
متن کاملElectron Spin Resonance in Organic Conductors Based on (BEDT-TTF) with Linear Anions
The Conduction Electron Spin Resonance (CESR) Spectroscopy which starts from classical works of Dyson (1), Feher and Kip (2) in 1955 was successively developed for simple metals. It appears this phenomena could be used as a unique instrument for the investigations of conduction electron kinetics. It becomes clear soon that a number of objects available for CESR observation is restricted because...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Acta Crystallographica Section A Foundations of Crystallography
سال: 2004
ISSN: 0108-7673
DOI: 10.1107/s0108767304094760